高效液相色谱法测定化妆品中依克多因的含量

建立高效液相色谱法测定化妆品中依克多因的分析方法,采用Agilent Poroshell 120 EC-C₁₈色谱柱（100 mm×3.0 mm,2.7μm）分离,以甲醇和p H为3.0的40 mmol/L磷酸二氢钠-10 mmol/L 1-庚烷磺酸钠缓冲溶液梯度洗脱,流速0.8 m L/min,柱温30℃,检测波长210 nm。采用外标法定量测定化妆品中的依克多因含量。结果表明,依克多因在5～800 mg/L的质量浓度范围内呈现良好线性关系,相关系数为0.999 8,方法的检出限和定量限分别为0.3和1.0 mg/L。该方法具有分离效率高、分析时间短、节省溶剂等优点,解决了依克多因在C₁₈色谱柱上保留弱的问题。     

Study on the removal of olefins from naphtha by clay loaded with trifluoromethanesulfonic acid

Journal of Porous Materials - In this work, a trifluoromethanesulfonic acid (TFOH) modified clay (TFOH-Clay) was developed for the removal of trace olefins in heavy naphtha. 5%TFOH-Clay can...     

纯净美妆产品的设计理念

以消费者、行业专家、各品牌商以及全球各个美妆相关行业对纯净美妆的认识为依据,从配方设计、关键的原料筛选、生产过程、包材选择以及测试评估等方面,对如何实现纯净美妆产品进行了较为详细的阐述,无疑为纯净美妆的标准建立和定义提供很好的参考.     

Synthesis of Janus polyaniline–polyelectrolyte complex membrane via in situ confined polymerization

Polyelectrolyte complex (PEC) membranes prepared from poly(styrene sulfonate) (PSS) and poly(diallyldimethylammonium chloride) (PDADMAC) were modified by crossflow polymerization of aniline (ANI). The PEC membranes were used as separators in a two-compartment setup where ANI monomer and ammonium persulfate (APS) oxidant diffused through the membranes to form polyaniline (PANI). APS and ANI having different distributions throughout the membranes, the reaction led to the asymmetric polymerization of PANI on one face of each PEC membrane thus producing Janus membranes. Due to the excess PANI content, the membrane displayed distinct asymmetric electrical conductivities on each face. Interestingly, very different ANI polymerizations were obtained when nonstoichiometric PEC membranes having different molar ratio of cationic and anionic polyelectrolytes (P⁺:P^? represents PDADMAC:PSS) were used and transport of APS was fastest through the 2:1 PEC when compared to the 1:2 PEC. In all experiments, the polymerization was most intense on the ANI side of the membranes. Also, the influence of NaCl both during PEC fabrication and during polymerization was studied and found to have some effect on the solute permeability. Results showed that a higher content of PANI was formed on PEC membranes having excess P⁺ and with no NaCl added during PEC fabrication. Although X-ray diffraction confirmed the presence of PANI on both sides of each membrane, scanning electron microscopy images demonstrated that both sides of each membrane had different PANI content deposited. Electrical conductivity measurements using a four-point probe setup also showed that the PEC–PANI exhibits asymmetric electrical property on different sides. © 2021 Society of Industrial Chemistry.     

双酚芴环氧树脂体系热性能和粘接性能研究

环氧树脂是一种性能优异的热固性树脂，在结构胶粘剂和纤维增强复合材料领域应用广泛。但是常见的环氧树脂体系耐热性普遍较差，近年来，航空航天领域对材料的热性能提出了更高的要求，常规的环氧树脂体系已经无法满足耐高温需求。针对该问题，我们设计了一种耐热性较高的双酚芴型环氧树脂体系，并对其热性能和粘接性能进行了研究。在本文中，首先采用流变学方法和DSC研究了其工艺性能，使用DMA和TGA法分析了环氧树脂体系的耐热性能，并通过单搭接剪切试验测试了该环氧体系的粘接性能。结果表明，双酚芴型环氧树脂体系可在180℃固化，固化后的玻璃化转变温度达到190℃，失重5%时的温度为392℃，150℃时的剪切强度为5.8 MPa，展现了优异的耐热性能和粘接性能。     

基于电信号特征分析的电机故障诊断技术

介绍了电机故障诊断技术平台的组成,分析了电机常见故障下电信号的特征。利用宜昌和景洪工厂两台电机进行了实际对比测试,宜昌工厂电机定子电流特征频率在49.2Hz时表现出峰值-36.08dB,在50.8Hz时表现峰值则为-37.23dB,表明电机存在转子断条故障;景洪工厂电机在转子特征频率为113.51Hz时,出现峰值-58.47dB,表明电机存在静态偏心故障。经电机现场抽芯检查,验证了电机故障快速诊断平台给出的电机健康状态评估结果,证实了基于电信号特征分析的电机故障诊断技术的准确性。     

南水北调中线总干渠藻类的生态调度

南水北调中线总干渠无在线调蓄水库,对藻类生态调度过程中出现的问题开展生态调度实现策略和实施方式研究。主要实现策略包括:划定自身的调蓄区,隔离生态调度对下游的影响;采用高效的渠池运行方式,减少生态调度时蓄量的反复调整;综合考虑安全、快速、平稳等需求,设定生态调度实施进程和方式。具体实施方式包括:将总干渠划分为流速调控区、调蓄区和正常运行区,分别实施等体积、控制蓄量和闸前常水位方式运行;将生态调度过程划分为充水阶段和泄水阶段,基于流速调控目标值、持续时长和水位降幅约束条件,确定各阶段时长和各分区的闸门群调控方案等。基于2018年3月输水工况,采用明渠一维非恒定流模型,仿真总干渠上游15个渠池的藻类生态调度过程。结果表明,生态调度可在3.5 d内完成,各渠池的平均流速由0.48 m/s增至0.93 m/s,持续时间超过2 h。在整个生态调度过程中,水位变化平稳,水位变幅符合安全阈值要求,下游渠道的正常运行未受生态调度明显影响。     

光栅对石墨烯太赫兹光学性质的影响

在不考虑等离激元诱导效应的情况下，利用玻尔兹曼平衡方程方法从理论上研究了金属光栅结构对石墨烯光电导率的直接影响。研究发现由于光栅对入射光的动量补偿作用，光栅对石墨烯的带内光电导率产生了显著的影响，使得在石墨烯的太赫兹吸收窗口区域出现光电导率峰，并且该光电导率峰可由光栅周期、电子浓度以及温度来调控。该研究有助于深入理解光栅结构对光电材料的影响，并表明光栅-石墨烯体系可以应用于可调谐的太赫兹光电器件，如太赫兹探测器。     

Performance Analysis of Linear and Hybrid Precoding on Massive MIMO System Using Truncated Polynomial Expansion

Wireless Personal Communications - In a communication system, ultra-wideband (UWB) is the most promising solution because of its high speed, high data rate, and short-range communication. However,...     

基于超声导波SC-DTW的金属板微损检测方法

针对金属板材的质量控制与服役性能评估问题,在对金属板材微损伤进行超声导波检测的基础上,结合形状上下文(shape context,SC)与动态时间规整方法对其损伤劣化程度进行量化评估.该方法以无损Lamb波信号为基准,采用动态时间规划(dynamic time warping,DWT)算法对损伤信号进行相似匹配分析对比,确定基准信号与损伤信号的最佳匹配路径.引入SC的轮廓识别方法对Lamb波的局部波形信息进行统计分析,以波形形状距离代替传统欧氏距离匹配方法,解决DTW相似匹配中的病态对齐问题.最后,将无损Lamb波与损伤Lamb波信号间SC-DTW匹配距离作为损伤程度的量化指标,采用随机闭合裂纹的有限元仿真模型和铝板弯折实验对所提出方法进行验证,结果表明,基于Lamb波SC-DTW的损伤量化指数对铝板早期裂纹具有较高的敏感性和较好的量化表征能力.该方法无需对波包进行识别,也不必进行复杂的特征提取,具有简单高效和抗噪声能力强等优点,在金属板服役性能评估与质量控制中有较好的实用性和推广价值.